It's very simple, just using left brace double times "{{" to output a normal left brace.
The following example is that converting a 3D point to string.
public string ToString(int d){
if (d < 0)
d = 0;
else if (d > 12)
d = 12;
string format = string.Format("({{0:N{0}}}, {{1:N{0}}}, {{2:N{0}}})", d, d, d);
return string.Format(format, X, Y, Z);
}